Brazing Rods

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Cu3P Electrolyzed in H2O NaCl and Vinegar?

I took my Cu3P (exact makeup of alloy can be found here http://www.bellmanmelcor.com/silvaloy_15.htm ) and used one piece as the anode and one piece as the cathode. The solution i made to do the electrolysis was water, table salt, and vinegar. I was trying to see if it was possible to extract the silver from the brazing rod, but i think i made several toxins. phosphorus, chlorine gas, and who knows what else. Can anybody tell me what I did? and if it was safe?

You got the chlorine (smell, color?) from oxidising chloride. the phosphorus probably ended up as phosphate at the anode.

Many reactiions are possible at the anode; chloride to chlorine; oxidation of Cu to Cu2+ which might end up as any of several insoluble materials; phosphorus in Cu3P to phosphite and phosphate.

But the chemistry could get really very complicated and many forms of phosphorus are unpleasant. If yuo are worried, carefully (eye protection, latex gloves) treat the mixture with household bleach or pool chlorine. But I think you're very unlikely to have done anything drastic.

the only cathode reactions would be deposition of copper and maybe formation of hydrogen.

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10PCS 32X230mm Aluminium Low Temperature Welding Soldering Brazing Repair Rod
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 1 16 2 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 1 8 1 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 2 Lb
RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 2 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 1 Lb
RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 1 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 1 8 5 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 5 Lb
RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 5 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 3 32 10 Lb
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RBCuZn C LFB Flux Coated Bronze Brazing Rod 39 x 1 8 2 Lb
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NASSAU RESEARCH CORP BRAZING RODS 18 long x 1 8 133 alloy rods
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SILVER BRAZE EASY FLO 45 OR EASY FLO 3 BY THE REG OUNCE IN RODS OR SHEET OR WIRE
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10PCS Aluminium Low Temperature Welding Soldering Brazing Repair Rod 32x230mm
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Blue Demon BDTP 125 01T Triple Play Low Temp Aluminum Zinc Brazing Rod 1 8 x 18
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